Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 3319 - 3330 (1988)
Update date:2022-08-11
Topics:
Gilbert, Bruce C.
Stell, Jonathan K.
Peet, Wendy J.
Radford, Karen J.
The chlorine atom (Cl.) has been generated in aqueous solution by reaction of Cl- with SO4.- and H2PO4., obtained by metal-catalysed decomposition of the appropriate peroxides.E.s.r. experiments in conjuction with a fast-flow method establish that Cl. is highly reactive, readly undergoing rapid addition, hydrogen-abstraction and electron-transfer reactions (k = 108-109 dm3 mol-1 s-1).The factors which influence the observed selectivity (energetics and polar effects) are discussed.
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