Hydroboration, followed by water addition of benchrotrenic alkenes. Formal dihydrogen addition

DOI: 10.1016/S0022-328X(96)06329-2

Source and publish data:

Journal of Organometallic Chemistry p. 283 - 286 (1996)

Update date:2022-08-11

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Authors:

Caro, Bertrand

Senechal-Tocquer, Marie-Claude

Senechal, Denis

Guen, Francoise Robin-Le

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Article abstract of DOI:10.1016/S0022-328X(96)06329-2

The reaction of the BH₃-THF reagent with benchrotrenic alkenes, followed by a water addition and the formation of hydrogenated products are described. This formation and the regioselectivity observed is a consequence of the electron withdrawing effect of the Cr(CO)₃ group.

Full text of DOI:10.1016/S0022-328X(96)06329-2

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