Selective radical-chain epimerisation at C-H centres α to oxygen under conditions of polarity-reversal catalysis

DOI: 10.1016/S0040-4039(99)00704-2

Source and publish data:

Tetrahedron Letters p. 4271 - 4274 (1999)

Update date:2022-08-29

Topics:

Authors:

Dang, Hai-Shan

Roberts, Brian P.

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Article abstract of DOI:10.1016/S0040-4039(99)00704-2

Polarity-reversal catalysis by tri-tert-butoxysilanethiol has been applied to promote radical-chain epimerisation selectively at carbon centres of the type R¹R²C*(H)OR.

Full text of DOI:10.1016/S0040-4039(99)00704-2

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