Reactions with Aziridines, XLVII: Regiospecificity and Stereoselectivity of Acid Catalyzed Alcoholysis of cis-2-Benzyl-3-phenyl-1-phenylsulfonylaziridine

DOI: 10.1002/ardp.19893220507

Source and publish data:

Archiv der Pharmazie p. 277 - 279 (1989)

Update date:2022-08-15

Topics:

Authors:

Stamm, Helmut

Speth, Dieter

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Article abstract of DOI:10.1002/ardp.19893220507

In ROH/H2SO4 the title compound is exclusively cleaved between N and C-3 yielding predominantly one diastereomer so that only a small portion of ring opening can proceed via a free carbenium ion.Ring opening shows an inverse dependence on the size of R.

Full text of DOI:10.1002/ardp.19893220507

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