Chemistry of Heterocyclic Compounds p. 264 - 271 (1980)
Update date:2022-08-05
Topics: Data Analysis Publication Reaction Mechanism Solvent Effects Experimental Setup Data Collection Kinetic Isotope Effect (KIE) Arrhenius Plot Data Interpretation
Lohkov, R.E.
A comparative study of the kinetics of the N oxidation of 19 derivatives of the pyridine series with perbenzoic acid in choroform and aqueous dioxane at 20, 25, 30, and 35 deg C was made.The rate constants, the parameters of the Arrhenius equation, and the activation energies of the N oxidation of the indicated monoazines were determined.The scale of the reactivities of the derivatives of the pyridine series was calculated within the framework of the Pearson hard-soft acid-base concept.
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Doi:10.1016/S0040-4039(00)82873-7
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