PENTACOORDINATE ORGANOSILICATE AS AN ALKYLATING REAGENT: PALLADIUM CATALYZED METHYLATION OF ARYL HALIDES

DOI: 10.1016/0040-4039(88)80026-1

Source and publish data:

Tetrahedron Letters p. 97 - 98 (1988)

Update date:2022-08-16

Topics:

Authors:

Hatanaka, Yasou

Hiyama, Tamejiro

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Article abstract of DOI:10.1016/0040-4039(88)80026-1

Under the influence of palladium catalyst, tris(diethylamino)sulfonium difluorotrimethylsilicate is found to deliver the methyl group to aryl halides highly chemoselectively, and the corresponding methylated aromatic compounds are produced in moderate to high yields.

Full text of DOI:10.1016/0040-4039(88)80026-1

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