A Convenient Synthesis of Aldehydes by Rearrangement of Cyclic Epoxides with Lithium Bromide on Alumina

DOI: 10.1055/s-1988-27588

Source and publish data:

Synthesis p. 394 - 395 (1988)

Update date:2022-08-11

Topics:

Authors:

Suga, Hisashi

Miyake, Hajimu

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Article abstract of DOI:10.1055/s-1988-27588

Epoxides can be converted effectively to aldehydes by rearrangement with lithium bromide supported on alumina.In the case of the alicyclic epoxides, ring contracted cycloalkanecarbaldehydes can be formed.The conversion is achieved by gas-phase reaction or in toluene as solvent.

Full text of DOI:10.1055/s-1988-27588

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