Tetrahedron Letters p. 3959 - 3960 (1981)
Update date:2022-08-16
Topics:
Girard, P.
Couffignal, R.
Kagan, H. B.
In THF solution at room temperature, a very fast reaction occurs between acid chlorides RCOCl and two equivalents of diiodosamarium.The α-diketone RCOCOR are obtained in yields from 40percent (R=alkyl) to 80percent (R=aryl).
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