Journal of the Chemical Society. Chemical communications p. 725 - 726 (1981)
Update date:2022-08-11
Topics:
Sasaki, Muneo
Bando, Masaichi
Inagaki, Yoh-ichi
Amita, Fujitsugu
Osugi, Jiro
The kinetics and the volume of activation of the title reaction to form 2-dibutylamino-p-benzoquinone in 1,2-dichloroethane and acetonitrile, -54 +/- 2 and -67 +/- 2 cm3/mol respectively, strongly support a reaction scheme in which ionic species are formed prior to the rate-determining step which is the second attack by the amine.
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