Synthesis p. 623 - 627 (1986)
Update date:2022-08-11
Topics:
Tsuji, Jiro
Minami, Ichiro
Shimizu, Isao
A useful method for the preparation of 1-alkenes from terminal allylic carbonates and acetates by the palladium-catalyzed reaction with formates is described.Formic acid-triethylamine is a suitable reductant.As catalyst, Pd2(dba)3CHCl3-P(n-Bu)3 gave the best result, 0.05-0.2 molpercent being sufficient (turnover 500-2000).Using this method, various 1-alkenes were prepared in good yields with high selectivity.
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Doi:10.1039/c39870001345
(1987)Doi:10.1016/S0957-4166(01)00135-5
(2001)Doi:10.1055/s-0040-1706551
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(2016)Doi:10.1016/j.inoche.2013.09.028
(2013)
