The Photochemical Reaction of Benzocinnoline. IV. Comments on the Mechanism of 2,2'-Diaminobiphenyl Formation

DOI: 10.1246/bcsj.54.2829

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2829 - 2830 (1981)

Update date:2022-08-11

Topics:

Authors:

Inoue, Hiroyasu

Hiroshima, Yukimi

Sakai, Toshihiko

Sakurai, Tadamitsu

Fukuda, Norio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.54.2829

In order to determine the mechanism of 2,2'-diaminobiphenyl formation from benzocinnoline, effect of aldehyde on the reaction was examined.It is proposed that ethanal, which was generated from ethanol in the initial photoreduction, formed an adduct with 5,6-dihydrobenzocinnoline, and that the resulting adduct participated in the subsequent photo-induced 2,2'-diaminobiphenyl formation.

Full text of DOI:10.1246/bcsj.54.2829

Products guided by the article

Product name:Propionaldehyde

Cas No:123-38-6

R&D Labs maybe for 123-38-6

Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China
Zibo Xiaoguang Chemical Material Co., Ltd

Contact:15954099116

Address:Boshan Development Zone
Qingdao S. H. Huanyu Imp. & Exp. Co., Ltd.

Contact:86-532-88250866

Address:Room 615, World Trade Centre Building B, Hongkong Middle Roda 6#, Qingdao, Shandong, China
EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA

Relevant to this article

Solvent and base dependence of copper-free palladium-catalyzed cross-couplings between terminal alkynes and arylic iodides: Development of efficient conditions for the construction of gold(III)/free-base porphyrin dimers

Doi:10.1021/jo052423v
(2006)
Tetra-benzothiadiazole-based [12]Cycloparaphenylene with Bright Emission and Its Supramolecular Assembly

Doi:10.1002/anie.202008505
(2020)
Doi:10.1021/ja00814a021
(1974)
Pyridine-3-carboxylic anhydride (3-PCA): A versatile, practical, and inexpensive reagent for condensation reaction between carboxylic acids and alcohols

Doi:10.1246/cl.2007.326
(2007)
Two-Dimensional Chemiresistive Covalent Organic Framework with High Intrinsic Conductivity

Doi:10.1021/jacs.9b03441
(2019)
Doi:10.1016/S0040-4039(01)84636-0
(1972)

Article Doi