Tetrahedron p. 6183 - 6204 (1999)
Update date:2022-08-11
Topics:
Penkett, Clive S.
Simpson, Iain D.
Irradiation of a series of 3-alkoxypyridinium tetrafluoroborate salts in alcohol solution resulted in the formation of cyclopentenone ketals by diastereoselective incorporation of the alcohol solvent under the basic conditions of the photolysis reaction. In a second series of photochemical reactions, the same 3-alkoxypyridinium salts were irradiated in water to yield β-hydroxycyclopentanones stereoselectively.
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