Journal of Organic Chemistry p. 5647 - 5648 (1989)
Update date:2022-08-16
Topics:
Kira, Mitsuo
Taki, Takayuki
Sakurai, Hideki
In apparent disagreement with the prediction by the Woodward-Hoffmann rule, facile intramolecular 1,3-silyl migration of allyl- and propargylsilanes with aromatic substituents at the silicon atom took place reversibly in various solvents under irradiation with 254-nm light, accompanied by the inversion of the silyl configuration.
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Doi:10.1007/BF00486675
(1988)Doi:10.1246/bcsj.62.816
(1989)Doi:10.1021/ol026156g
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(2010)Doi:10.1002/anie.201000105
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(1989)
