Tetrahedron Letters p. 5825 - 5828 (1988)
Update date:2022-08-29
Topics:
Harwood, Laurence M.
Jones, Geraint
Pickard, John
Thomas, Royston M.
Watkin, David
The stereochemical outcome of intramolecular Diels-Alder reactions of furans with Z- and E-2-ene-1,4-dione units attached by a bridging chain to C-2 of the furan results from modification of the steric demands of the bridging chain by the preference of the external activating group to adopt an endo- stereochemistry.
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