
Bulletin of the Chemical Society of Japan p. 222 - 224 (1984)
Update date:2022-08-17
Topics:
Abe
Horii
Taniguchi
Kinetic studies of the oxidation of 2,3-dihydroxy-2-propenal (triose reductone) by the peroxodisulfate ion (S//2O//8**2** minus ) were carried out between pH 4. 1 and 5. 9 at various temperatures (10-30 degree C) and for ionic strengths (I) (0. 07 to 1. 07 m (1 m equals 1 mol dm** minus **3) which were adjusted using NaClO//4. The pH dependence of the reaction rates revealed that the singly-charged anion (RH** minus ) was chiefly responsible for the reaction, while undissociated reductone was inactive to peroxodisulfate ion.
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