Journal of Physical Chemistry p. 2543 - 2548 (1992)
Update date:2022-08-17
Topics:
Johnson, D. E.
Whitehead, J. C.
Walters, E. A.
Dorko, E. A.
The reaction between F2 and CF3I has been investigated over a wide range of pressures and flow velocities at 298 K.An induction time precedes a period of CF3I consumption which is well characterized by an exponential decrease in concentration over time.The CF3I disappearance rate as well as the induction time are dependent upon the concentration of the initial species, indicating that a chain reaction is responsible.CF3I and F2 react to give IF5, C2F6, and CF4 as end products (where the principal carbon-containing end product is CF4), suggesting that both IF and CF3 play an important role in the kinetics of the reaction.The apparent discrepancies of the previous studies of this reaction are shown to be related to experimental conditions.
Nanjing Raise Pharmatech Co., Ltd
website:http://www.raisechem.com
Contact:+86-25-58649566
Address:B381,No.606,Ningliu Road,Jiangbei New Area,Nanjing,Jiangsu Province,China
Shanghai Dianyang Industry Co.,ltd
Contact:+86 21 6492 4669
Address:Chejing RD, Songjiang District, Shanghai, China
HAINAN JINYING IMPORT AND EXPORT CO. LTD
Contact:+86-898-32875423
Address:A SECTION 19TH FL, TIMES SQUARE, NO.2 GUO MAO AVENUE HAIKOU, HAINAN, P. R. OF CHINA
Chuzhou Baiao Biologhy S&T Co., Ltd.
Contact:+86-25-83212599；+86-25-83212699 13705185959
Address:Room 905, Tianzheng International Platza, No.399, Zhongyang Road ,Nanjing, Jiangsu Province, China
Shanghai birch chemical technology co.,ltd
Contact:+86-21-54096810
Address:No.2588,Jungong Road,Shanghai,China
Doi:10.1039/b600736h
(2006)Doi:10.1021/ja00895a033
(1963)Doi:10.1016/j.tetlet.2004.08.032
(2004)Doi:10.1016/j.jorganchem.2017.05.018
(2017)Doi:10.1021/acs.oprd.9b00073
(2019)Doi:10.1055/s-2001-18054
(2001)
