Cobalt-catalysed Reaction of Carbon Monoxide-Hydrogen Mixtures in Alkoxy-terminated Polyglycol Solvents

DOI: 10.1039/c39810000618

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 618 - 619 (1981)

Update date:2022-08-24

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Authors:

Paxson, Timm E.

Reilly, Charlie A.

Holecek, Dale R.

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Article abstract of DOI:10.1039/c39810000618

Under pressures of ca. 200 bar (3000 lb in^-2) in CO-H2 at ca. 200 - 250 deg C in methoxy-terminated polyglycol (glyme) solvents, , cobalt carbonyls catalyse the formation of a number of oxygenated products in which ethanol predominates (up to 70 percent selectivity); experiments with 13C labelled CO and unlabelled diglyme suggest that > 90 percent of the ethanol was derived from the solvent and only ca. 5 percent from pure syn gas chemistry.

Full text of DOI:10.1039/c39810000618

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