Tetrahedron Letters p. 8077 - 8080 (1994)
Update date:2022-08-30
Topics:
Lassila, Kevin R.
Waller, Francis J.
Werkheiser, Steven E.
Wressell, Amy L.
Aldehyde-mediated olefin epoxidations appear to proceed by parallel peracid and radical addition pathways.For that portion of the reaction proceeding by radical addition, several lines of evidence favor an explanation in which the peroxyacyl-olefin adduct decomposes in a concerted manner to form alkyl radical, CO2, and epoxide.
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