Journal of the Chemical Society. Chemical communications p. 93 - 94 (1994)
Update date:2022-08-29
Topics:
Bleasdale, Christine
Golding, Bernard T.
Lee, Won Heui
Maskill, H.
Riseborough, Jane
Smits, Elly
In methanolic aqueous acid, methoxy-substituted tritylammonium ions undergo heterolysis to give an equilibrium mixture of the substituted trityl cation, the corresponding alcohol (and methyl ether), and the ammonium cation via an SN1 mechanism; the detection of a reaction channel first order in hydronium ions may implicate substituted trityl cation-ammonia (ion-molecule) pairs as reactive intermediates.
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