Tetrahedron p. 2591 - 2594 (1982)
Update date:2022-08-29
Topics:
Singh, Bharat
Samant, A. K.
Saxena, B. B. L.
The oxidation kinetics of methyl vinyl ketone and isopropyl methyl ketone by chloramine-T in aqueous alkaline solutions show first-order dependence on chloramine-T, both substrates and alkali.No effect of p-toluenesulphonamide was evident.Observed stoichiometry, negligible effect of ionic strength and a positive dielectric effect point to a mechanism involving interaction of enolate anions with chloramine-T in the rate determining step.Activation parameters and the isolation of the product formaldehyde are in agreement with the proposed mechanism.
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