Journal of Organometallic Chemistry p. 69 - 72 (1981)
Update date:2022-08-16
Topics:
Mugnier, Y.
Moise, C.
Laviron, E.
The electrochemical oxidation of titanocene monochloride, Cp2TiClL (L=tetrahydrofuran or dimethylphenylphosphine), has been studied by voltammetry on a disc electrode, by linear potential sweep voltammetry and by controlled potential electrolysis.A first one electron step yields Cp2TiClL+, which then reacts with Cp2TiClL to give Cp2TiCl2 and Cp2TiL+2.The latter is oxidized to Cp2TiL2+2
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Doi:10.1021/acs.jmedchem.6b01393
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