REACTION OF METALLOCENYL THIOKETONES WITH C5H5- AND - ANIONS. PREPARATION AND CRYSTAL STRUCTURES OF DIMERIC CYMANTRENYLPHENYLFULVENE DERIVATIVES

DOI: 10.1016/0022-328X(85)80186-8

Source and publish data:

Journal of Organometallic Chemistry p. 341 - 354 (1985)

Update date:2022-08-11

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Authors:

Batsanov, A. S.

Dolgova, S. P.

Bakhmutov, V. I.

Struchkov, Yu. T.

Setkina, V. N.

Kursanov, D. N.

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Article abstract of DOI:10.1016/0022-328X(85)80186-8

Ferrocenyl- and cymantrenyl-phenylthioketone react with C5H5^- or <(C5H5)Fe(CO)2>^- anions forming ferrocenyl- and cymantrenyl-phenylfulvene.The latter readily undergoes a Diels-Alder dimerization or a cycloaddition with a starting thioketone or analogous ketone.Crystal structures of two dimeric products were established.

Full text of DOI:10.1016/0022-328X(85)80186-8

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