Stereospecific 1,2-Rearrangement of Cyclopropyl Group. Synthesis of Chiral α-Cyclopropyl Ketones and α-Cyclopropyl Aldols

DOI: 10.1016/S0040-4039(01)80589-X

Source and publish data:

Tetrahedron Letters p. 5443 - 5446 (1989)

Update date:2022-08-15

Topics:

Authors:

Shimazaki, Masato

Hara, Hisaaki

Suzuki, Keisuke

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Article abstract of DOI:10.1016/S0040-4039(01)80589-X

Stereospecific 1,2-rearrangement of cyclopropyl group is described as an efficient route to stereo-defined α-cyclopropyl ketones and α-cyclopropyl aldols.Acceleration of the reaction by the introduction of trimethylsilyl(TMS) group to the α-position of cy

Full text of DOI:10.1016/S0040-4039(01)80589-X

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