Bulletin of the Chemical Society of Japan p. 2229 - 2231 (1988)
Update date:2022-08-17
Topics:
Ishida, Akito
Yamashita, Shinya
Takamuku, Setsuo
A EuIII/EuII photoredox system in alcohol induced an effective hydroxyalkylation at an α-position of a dialkyl malonate.The alcohol adduct was then converted to the lactone.A step-by-step hydroxyalkylation mechanism was suggested in which the Eu ion is used as a photocatalyst and also as a condensation catalyst for the reaction of dialkyl malonates and aldehydes.
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