Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 877 - 883 (1991)
Update date:2022-08-29
Topics:
Volod'kin, A. A.
A kinetic scheme is proposed for the reaction of 2,6-di-t-butylphenol with methyl acrylate in the presence of potassium 2,6-di-t-butylphenolate.Rate constants have been calculated for the elementary stages which describe the mechanism of catalysis and the effect on the kinetic laws of the proton-donor components 2,6-di-t-butylphenol, water, and methanol.The kinetic scheme contains 30 components and includes 62 rate constants for the elementary stages, which were calculated by mathematical modeling of the kinetics of the process.The calculated results are compared with experimental data for the dependence of the rate of consumption of 2,6-di-t-butylphenol on the concentration of potassium 2,6-di-t-butylphenolate and on the concentrations of the proton-donor components.
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