Nickel acetylacetonate-induced 1,4-additions of 1-alkenyl(disiamyl)boranes to α,β-unsaturated ketones, esters and nitriles

Article abstract of DOI:10.1080/00397919608004563

The conjugate addition of 1-alkenyl(disiamyl)boranes to α,β-unsaturated ketones, esters, or nitriles was carried out in the presence of Ni(acac)₂ and triethylamine in DMF. The reactions provided γ,δ-unsaturated ketones, esters, and nitriles in

Full text of DOI:10.1080/00397919608004563

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Synthetic Communications: An
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Nickel Acetylacetonate-
Induced 1,4-Additions of 1-
Alkenyl(Disiamyl)Boranes to
α,β-Unsaturated Ketones,
Esters and Nitriles
Teiji Yanagi a , Hirotomo Sasaki a , Akira Suzuki a
Norio Miyaura a
&
a Division of Molecular Chemistry, Faculty of
Engineering , Hokkaido University , Sapporo, 060,
Japan
Published online: 23 Aug 2006.
To cite this article: Teiji Yanagi , Hirotomo Sasaki , Akira Suzuki & Norio Miyaura
(1996) Nickel Acetylacetonate-Induced 1,4-Additions of 1-Alkenyl(Disiamyl)Boranes
to α,β-Unsaturated Ketones, Esters and Nitriles, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 26:13,
2503-2509, DOI: 10.1080/00397919608004563
To link to this article: http://dx.doi.org/10.1080/00397919608004563
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