Bulletin of the Chemical Society of Japan p. 1585 - 1586 (1981)
Update date:2022-08-12
Topics:
Yamanaka, Tohr
Imai, Takashi
The formation of monoesters of the C4-14-α,ω-alkanediol (1) with stearic and/or palmitic acids and the consecutive pyrolysis of the monoesters to an ω-alken-1-ol (2) were effected at 320-350 deg C under 260-760 mmHg in a backmix flow reactor of a constant volume equipped with a fractionating column, through which the unchanged 1 was partially recycled.The selectivity in the preparations of 2(C6, C10, C14) was greater than 79percent.
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