Tetrahedron p. 593 - 598 (1998)
Update date:2022-08-12
Topics:
Rothenberg, Gadi
Yatziv, Yael
Sasson, Yoel
Autoxidation reactions of 3-Carene 1 and α-Pinene 2 were performed using various homogeneous catalysts. Different product and regio- selectivities were observed. The factors that promote hydrogen abstraction (HA) reactions in both molecules are discussed, and it is proposed that the difference in the product selectivities is due to the lack of 'cyclic activation' in 2. Oxidation of 1 produced mainly 3-carene-5-one 3, while 2 yielded 2,3-epoxypinane 6 as the major product.
View More
Jiangsu Cale New Material Co.ltd
Contact:+86-515-88334667/88203550
Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Contact:+86-512-56795332
Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
Contact:+86-0760-85282375
Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Shandong Topscience Biotech Co., Ltd.
Contact:0633-2619278
Address:No. 98 Lanshan West Road, Lanshan District, Rizhao, Shandong Province, P.R. of China
JIN TAN CHENG'EN CHEMICAL CO.,LTD.
Contact:86-519-82116250
Address:NO.102，village Dongfang，conomic development zone
Doi:10.1016/j.catcom.2013.01.016
(2013)Doi:10.1021/ja01516a069
(1959)Doi:10.1007/BF01187679
()Doi:10.1134/S0036024410070058
(2010)Doi:10.1007/s00706-002-0528-1
(2003)Doi:10.1007/s10562-012-0805-5
(2012)
