Bulletin of the Chemical Society of Japan p. 2345 - 2350 (1999)
Update date:2022-08-28
Topics:
Terao, Yoshito
Satoh, Tetsuya
Miura, Masahiro
Nomura, Masakatsu
A number of carbonyl and phenolic compounds efficiently couple with o- dibromobenzenes in the presence of a palladium catalyst and a base to give the corresponding oxygen-containing heterocycles or carbocyclic compounds. Thus, from the reactions of benzyl phenyl ketones, 1-naphthols, and α,β- unsaturated aldehydes and ketones, benzofuran, benzopyran, benzocyclobutane, and indene derivatives, respectively, are produced selectively via the successive formation of C-C and C-O bonds or of two C-C bonds.
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