SPALTUNG VON TETRAMETHYLDISTIBAN MIT BROM, IOD UND METHYLIODID. BILDUNG DES ADDUKTS MeSbI2*2Me4SbI

Article abstract of DOI:10.1016/S0022-328X(00)98575-9

Very pure halides Me2SbX (X - Br, I) are obtained by cleavage reactions of Me2SbSbMe2 with equimolar amount of Br2 or I2.Me3Sb and Me2SbI are formed in the reaction of Me2SbSbMe2 and MeI and a 1/1 molar ratio.With excess MeI the products are: Me4SbI2 and an adduct of composition MeSbI2 * 2Me4SbI, which can also be formed by the reaction of its components.