Stereoselective Synthesis of (E) and (Z)-Vinylsilane by the Addition Reaction of Organometallic Reagent to Silyl-substituted Fischer-type Carbene Complex

DOI: 10.1246/cl.1994.231

Source and publish data:

Chemistry Letters p. 231 - 234 (1994)

Update date:2022-08-16

Topics:

Authors:

Iwasawa, Nobuharu

Saitou, Masatoshi

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Article abstract of DOI:10.1246/cl.1994.231

The addition reaction of organolithium or Grignard reagents to pentacarbonylmolybdenum is examined, and either (E)- or (Z)-vinylsilanes are obtained with high selectivities depending on the reaction conditions.

Full text of DOI:10.1246/cl.1994.231

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