Rhodium-catalyzed intermolecular silylcarbamoylation of acetylenic bonds

Article abstract of DOI:10.1016/S0040-4039(99)00200-2

α,β-Unsaturated amides are readily formed by silylcarbamoylation of an acetylenic bond which is accomplished intermolecularly by a one-pot reaction of four components, an alkyne, a hydrosilane, an amine, and CO in the presence of a catalytic amount of Rh<