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Synthesis of cis-Olefins via Palladium-Catalyzed Coupling of Organic Halides, Norbornadiene, and Organotin Compounds

DOI: 10.1246/bcsj.66.3522

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3522 - 3524 (1993)

Update date:2022-08-16

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Authors:

Kosugi, MasanoriKosugi, Masanori

Kimura, TomoyukiKimura, Tomoyuki

Oda, HiroshiOda, Hiroshi

Migita, ToshihikoMigita, Toshihiko

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Article abstract of DOI:10.1246/bcsj.66.3522

Palladium-catalyzed cross-coupling of organic halides with organotin compounds in the presence of norbornadiene gave 5,6-disubstituted norbornene, which was treated by a retro Diels-Alder reaction yielding cis-ethene and cyclopentadiene.

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Full text of DOI:10.1246/bcsj.66.3522

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