Synthesis of optically pure cis epoxyalcohols via an enzymatic route; an alternative to the sharpless asymmetric epoxidation

DOI: 10.1016/0040-4039(91)80682-V

Source and publish data:

Tetrahedron Letters p. 3043 - 3046 (1991)

Update date:2022-08-12

Topics:

Authors:

Grandjean

Pale Pale

Chuche Chuche

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Article abstract of DOI:10.1016/0040-4039(91)80682-V

Optically pure (2S, 3R)-4-butyryloxy-2,3-epoxybutan-1-ol 2b and (2R, 3S)-4-tert-butyldiphenylsilyloxy-2,3-epoxybutan-1-ol 5, starting materials for the synthesis of enantiomeric epoxyalcohols 3 and 4, were obtained after enzymatic hydrolysis of meso cis-2,3-epoxybutane-1,4-diol diesters 1b.

Full text of DOI:10.1016/0040-4039(91)80682-V

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Product name:Oxiranemethanol, 3-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-, (2R,3S)-

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