Tetrahedron p. 6169 - 6174 (1988)
Update date:2022-08-11
Topics:
Kulkarni, V. S.
Kulkarni, N. N.
Lele, S. R.
Hosangadi, B. D.
Photochemical studies on 7,8,12,14,16 and 20 membered cyclic esters have been carried out in benzene and methanol.Decarboxylation and solvolysis ascribable to β- and α-scission respectively are observed in case of seven and eight membered cyclic esters.Larger rings do not undergo these photoreactions thus demonsrating effect of ring size on photoreactivity.
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