Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 517 - 521 (1990)
Update date:2022-08-29
Topics:
Moiseenkov, A. M.
Cheskis, B. A.
Shpiro, N. A.
Stashina, G. A.
Zhulin, V. M.
The dimerization of methyl acrylate to dimethyl α-methyleneglutarate by the action of tributylphosphine in the absence of a solvent was investigated.Methyl α-methylene-β-hydroxypentanoate was obtained with a moderate yield by the condensation of propionaldehyde with methyl acrylate catalyzed by triphenylphosphine or 1,4-diazabicyclo<2.2.2>octane and initiated by high pressure.In the last of these data a three-stage stereospecific synthesis of dominicalures 1 and 2 (components of the aggregation pheromone of the grain beetle) was realized from sec-amyl acrylate and propionaldehyde or isobutyraldehyde.
View More
Contact:86-512-87182055
Address:No.128 Fangzhou Rd, Suzhou Industrial Park, China, 215125, China
Shenzhen Sunrising Industry Co., ltd.
Contact:+86 755 86571158 / 86571159 / 86571160
Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Contact:+86-535-8888888
Address:No.161 Haishi Rd.
Contact:+86-20-38011066
Address:3510, Diwang Commercial Center, 5002 Shennan Rd, Shenzhen, P.R.China
shanghai jinshan pharmaceutical Co.,Ltd
Contact:021-57363011，13681638167
Address:No. 7966 Tingfeng Road,Jinshan,Shanghai,China
Doi:10.1002/jms.1190300616
(1995)Doi:10.1016/S0022-328X(00)86864-3
(1972)Doi:10.1080/00397911.2010.519845
(2011)Doi:10.1021/acs.jpca.8b00557
(2018)Doi:10.1080/00397910600781232
(2006)Doi:10.1021/jm9706980
(1998)
