Journal of Organic Chemistry p. 4717 - 4720 (1985)
Update date:2022-08-11
Topics:
Wiberg, Kenneth B.
Martin, Eric J.
Squires, Robert R.
The enthalpies of hydrolysis of a series of ortho esters have been measured in aqueous dioxane.The largest effect on ΔHr was found with α-branching, in contrast to the previously reported hydrolysis of ketals which gave the larger effect with β-branching.Possible reasons for this difference in behavior are discussed.
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