Direct transformation of O-glycosides into other O-glycosides using trimethylsilyl bromide and zinc bromide

DOI: 10.1248/cpb.40.1042

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1042 - 1043 (1992)

Update date:2022-08-11

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Authors:

Higashi Higashi

Nakayama

Shioya Shioya

Kusama Kusama

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Article abstract of DOI:10.1248/cpb.40.1042

We have succeeded in developing a novel glycosidation catalyzed by a combination of trimethylsilyl bromide (TMSBr) and a Lewis acid using simple O-glycosides as glycosyl donors. Treatment of benzyl 2-deoxy-2-trichloroethoxycarbonylamino-D-glucopyranoside

Full text of DOI:10.1248/cpb.40.1042

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