Stereochemistry at the Phosphorus Atom during Palladium-catalysed Formation of Carbon-Phosphorus Bonds and Mechanistic Implications

DOI: 10.1039/c39860001606

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1606 (1986)

Update date:2022-08-30

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Authors:

Xu, Yuanyao

Zhang, Jing

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Article abstract of DOI:10.1039/c39860001606

The reaction of (R)-(+)-isopropyl methylphosphinate (5) with bromobenzene in the presence of Pd(0) catalyst and triethylamine to afford (S)-(-)-isopropyl methylphenylphosphinate (6) proceeds with complete retention of configuration via a front-sided attack by phenylpalladium bromide on the phosphorus nucleophile.

Full text of DOI:10.1039/c39860001606

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