Synthesis p. 299 - 302 (1995)
Update date:2022-08-10
Topics:
Kabbara
Hoffmann
Schinzer
Vinyl halides containing vinylic and allylic silane terminators undergo a stereospecific palladium(0)-catalyzed cross-coupling with derivatives of terminal propargylic and homopropargylic alcohols to polyunsaturated silanes. Basic stable and unstable protecting groups were tolerated under slightly different reaction conditions.
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(1928)