Syntheses and characterization of 1,1'-bis(3-pyridylethynyl)ferrocene and 1,1'-bis(4-pyridylethynyl)ferrocene

Article abstract of DOI:10.1080/10426500108546628

Two novel disubstituted ferrocene, 1,1'-bis(3-pyridylethynyl)ferrocene 1 and 1,1'-bis(4-pyridylethynyl)ferrocene 2, were synthesized and fully characterized by elemental analysis, ¹H NMR ¹³C NMR IR, and X-ray crystallography. Compound 1crystallizes in monoclinic, space group Cc, a=17.26?, b=9.77?, c=10.85?, β=105.45; R₁ =0.0399, wR₂=0.1077, GooF=1.023. The two arms of the ferrocene are parallel, which will play an important role both in the coordination chemistry and electronic communiculion of the ferrocene.

Full text of DOI:10.1080/10426500108546628

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Phosphorus, Sulfur,
and Silicon and the
Related Elements
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Syntheses and
Characterization
of 1,1'-Bis(3-
Pyridylethynyl)Ferrocen
and 1,1'-Bis(4-
Pyridylethynyl)Ferrocen
Ekkehard Lindner , Ruifa Zong &
Klaus Eichele
a Institut für Anorganische
Chemie, Auf der Morgenstelle 18,
Universität Tübingen , D-72076
Tübingen, Germany
b Institut für Anorganische
Chemie, Auf der Morgenstelle 18,
Universität Tübingen , D-72076
Tübingen, Germany
c Institut für Anorganische
Chemie, Auf der Morgenstelle 18,

Universität Tübingen , D-72076
Tübingen, Germany
Published online: 02 Apr 2008.
To cite this article: Ekkehard Lindner , Ruifa Zong & Klaus
Eichele (2001) Syntheses and Characterization of 1,1'-Bis(3-
Pyridylethynyl)Ferrocene and 1,1'-Bis(4-Pyridylethynyl)Ferrocene,
Phosphorus, Sulfur, and Silicon and the Related Elements, 169:1,
219-222, DOI: 10.1080/10426500108546628
To link to this article: http://
dx.doi.org/10.1080/10426500108546628
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