Tetrahedron Letters p. 8637 - 8640 (1996)
Update date:2022-08-11
Topics:
Moher, Eric D.
The first preparation of enantiomerically pure bicyclo[3.1.0]hexane-2-one-6-carboxylic acid ethyl ester (1), a valuable synthetic intermediate, is described. The synthesis features a retro-Diels-Alder reaction as a key step. Conditions which allow for a high yielding thermal conversion of 3 to 4 are described.
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Doi:10.1071/CH04006
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(1998)Doi:10.1246/bcsj.55.909
(1982)
