Tetrahedron Letters p. 789 - 792 (1992)
Update date:2022-08-29
Topics:
Yasui, Kengo
Fugami, Keigo
Tanaka, Shuji
Tamaru, Yoshinao
Ii, Atsuhiko
Yoshida, Zen-Ichi
Saidi, Mohamad R.
Pd(II) salts catalyze the rearrangement of 1-allyloxy-1-siloxycyclopropanes to provide a mixture of Δ2-, Δ3- and Δ4-hexenonic acids. This rearrangement proceeds via a double bond isomerization followed by a ring opening of
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