Palladium(II) catalyzed novel rearrangement of 1-allyloxy-1-siloxycyclopropanes

DOI: 10.1016/S0040-4039(00)77716-1

Source and publish data:

Tetrahedron Letters p. 789 - 792 (1992)

Update date:2022-08-29

Topics:

Authors:

Yasui, Kengo

Fugami, Keigo

Tanaka, Shuji

Tamaru, Yoshinao

Ii, Atsuhiko

Yoshida, Zen-Ichi

Saidi, Mohamad R.

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Article abstract of DOI:10.1016/S0040-4039(00)77716-1

Pd(II) salts catalyze the rearrangement of 1-allyloxy-1-siloxycyclopropanes to provide a mixture of Δ²-, Δ³- and Δ⁴-hexenonic acids. This rearrangement proceeds via a double bond isomerization followed by a ring opening of

Full text of DOI:10.1016/S0040-4039(00)77716-1

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