Journal of the American Chemical Society p. 541 - 546 (1981)
Update date:2022-08-11
Topics:
Schrauzer, Gerhard N.
Grate, John H.
Sterically hindered secondary alkylcobalamins carrying hydrogen in the β-position decompose in neutral aqueous solutions spontaneously by way of β-elimination.The cleavage of the Co-C bond in these compounds is caused by "upward" distortions of the corrin
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