Selective Reductive Cleavage of Arenocrown Ethers by Alkali Metals in THF

DOI: 10.1021/jo00113a014

Source and publish data:

Journal of Organic Chemistry p. 2365 - 2367 (1995)

Update date:2022-08-17

Topics:

Authors:

Sokol, Maria

Kowalczuk, Marek

Grobelny, Zbigniew

Janeczek, Henryk

Jedlinski, Zbigniew

et al. et al.

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Article abstract of DOI:10.1021/jo00113a014

Alkali metal solutions in tetrahydrofuran containing the arenocrown ethers naphtho-15-crown-5, benzo-15-crown-5, and benzo-18-crown-6 were investigated using 39K NMR, ESR, and GC-MS techniques.The cleavage of carbon-oxygen bonds in the crown ethers studied is discussed.

Full text of DOI:10.1021/jo00113a014

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