New chiral diphosphines, 2,3-Bis(siloxy)-1,4-bis(diphenylphosphino)butanes, and their cationic Rh(I) complexes: Synthesis and structures

DOI: 10.1246/cl.1996.1007

Source and publish data:

Chemistry Letters p. 1007 - 1008 (1996)

Update date:2022-08-11

Topics:

Authors:

Tamao, Kohei

Nakamura, Kazunori

Yamaguchi, Shigehiro

Shiro, Motoo

Saito, Seiki

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Article abstract of DOI:10.1246/cl.1996.1007

A series of 2,3-bis(siloxy)-1,4-bis(diphenylphosphino)butanes SILOPs, possessing various siloxy groups, and their Rh(I) complexes have been prepared. The X-ray structure of a SILOP shows a staggered conformation with two siloxy groups in the anti position

Full text of DOI:10.1246/cl.1996.1007

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