Inorganic Chemistry p. 492 - 495 (1963)
Update date:2022-08-11
Topics:
Hoekstra, Henry R.
Infrared absorption curves for carefully purified samples of UO2F2 and UO2CO3 have been obtained. Using the new frequencies and Badger's rule, the uranyl bond lengths are calculated as 1.71 ?. in UO2F2 and 1.72 ?. in UO2CO3, in very good agreement with the Zachariasen bond length-bond strength relationship. Evidence is given to show that the U-O bond length in different uranyl salts shows relatively little variation (1.71-1.76 ?.) and that the bond order in the simple anhydrous salts may approach three.
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