Tetrahedron p. 3673 - 3686 (1994)
Update date:2022-08-24
Topics:
Toyota, Masahiro
Seishi, Takashi
Fukumoto, Keiichiro
Diastereoface-selective Pd2+-promoted cycloalkenylation reaction (22→24) has been employed as the key step for a conceptually new and highly diastereocontrolled formal total synthesis of - -stemodin (1). Interestingly, the synthetic intermediat
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