Silver fluoroborate promoted sulfur alkylation of β-silyl ethyl sulfides. Selective synthesis of β-thioglycosides

Article abstract of DOI:10.1080/00397919408011323

Silver (I) activation of α-glucosyl bromide in the presence of 2-trimethylsilylethyl sulfides as sulfur nucleophiles selectively provides β-thioglycosides.

Full text of DOI:10.1080/00397919408011323

This article was downloaded by: [Computing & Library Services, University
of Huddersfield]
On: 02 January 2015, At: 06:41
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
Silver Fluoroborate Promoted
Sulfur Alkylation of β-Silyl Ethyl
Sulfides. Selective Synthesis of
β-Thioglycosides
Anu Mahadevan a , C. Li a & P. L. Fuchs a
a Department of Chemistry , Purdue University ,
West Lafayette, Indiana, 47907
Published online: 23 Sep 2006.
To cite this article: Anu Mahadevan , C. Li & P. L. Fuchs (1994) Silver Fluoroborate
Promoted Sulfur Alkylation of β-Silyl Ethyl Sulfides. Selective Synthesis of
β-Thioglycosides, Synthetic Communications: An International Journal for
Rapid Communication of Synthetic Organic Chemistry, 24:21, 3099-3107, DOI:
10.1080/00397919408011323
To link to this article: http://dx.doi.org/10.1080/00397919408011323
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and

are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions