Preparation and crystal structure of (COD)(p-tolyl-N=PPh2CHPPh2NH-p-tolyl)>-. A rhodium(I) complex containing a new ?-N,?-C-chelating iminophosphoranylmethanide ligand

DOI: 10.1016/0022-328X(89)87016-0

Source and publish data:

Journal of Organometallic Chemistry p. C61 - C74 (1989)

Update date:2022-08-11

Topics:

Authors:

Imhoff, P.

Elsevier, C. J.

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Article abstract of DOI:10.1016/0022-328X(89)87016-0

Reaction of the bis(iminophosphoranyl)methane <(p-tolyl-N=PPh2)2CH2> with 2 (L = CO or L2 = COD) yields two different types of compounds.In one of these the bis(iminophosphoranyl)methane ligand is coordinated in a ?-N,?-N'-chelating mode to form s

Full text of DOI:10.1016/0022-328X(89)87016-0

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